Hazard assessment for non-toxic substances in relation to European marine sites

Substance

Sources

Fate and Behaviour

Effects

Point

Diffuse

Partitioning to air, water and sediments

 
Nitrogen Sewage discharges;

Industrial discharges

Atmospheric deposition,

Coastal water inputs,

Agricultural run-off

Cycles between sediment, water and the atmosphere. Can accumulate in sediment as organic matter increases (with greater N-load) then dies entering sediment Can be toxic to invertebrates and fish (NH3);

Can contribute to deoxygenation of the water column and sediments (nitrification and eutrophication);

Can contribute to stimulation of algal growth (eutrophication).

Phosphorus Sewage discharges; Industrial discharges Coastal water inputs;

Agricultural run-off;

Natural catchment run-off; Some input from wind-blown pollen and dust.

Cycles between sediment and water.

Accumulates in sediments

Can contribute to stimulation of algal growth (eutrophication);

Can contribute to deoxygenation of water column and sediments (eutrophication).

Silicon Has been associated with detergent manufacture Soil erosion;

Weathering of rocks;

Sediment mineralisation

Accumulates in sediments. Cycles between water and sediments; never reaches saturation point in water. Spring diatom blooms may strip silicon from the water column.

 

 

Can contribute to stimulation of algal growth (eutrophication);

Can contribute to deoxygenation of water column and sediments (eutrophication).

Organic carbon Sewage discharges; Industrial discharges Agricultural run-off;

Natural catchment run-off;

Primary productivity within the aquatic environment

Cycles between water column, sediments, and atmosphere through biological and chemical processes.

Can accumulate in sediments.

Can contribute to stimulation of production of primary consumers (organic enrichment);

Can contribute to deoxygenation of water column and sediments (organic pollution)

Oxygen depleting substances Sewage discharges; Industrial discharges Water column:

Bacterial and algal respiration.

Chemical oxidation

Sediments:

Agricultural run-off;Natural catchment run-off;

Primary production;

Decaying algal blooms.

Dissolved and particulate organic matter can deplete oxygen in the water column (measured as BOD).

Particlulate organic matter can accumulate in sediments and delete oxygen (measured as SOD)

Nitrification in sediments (measured as SOD)

Can be toxic to invertebrates and fish at low concentrations;
 

pH

Industrial discharges Atmospheric deposition (acid rain pH can be decreased in the water column. Can contribute to transient changes in water chemistry.
Salinity Major sewage and industrial discharges discharges (reduce salinity) Coastal water inputs (increase salinity);

River inputs (reduce salinity;

Atmospheric inputs (reduce salinity).

Salinity can be increased or reduced in the water column and sediments. Reduced salinity can have lethal and sub-lethal effects on marine organisms;

Can influence toxicity of ammonia;

 

 

Turbidity Sewage discharges;

Industrial discharges. Dredging operations

Sediment resuspension; Coastal erosion; Phytoplankton;

Coastal water inputs; Dissolved and particulate organic matter.

Can remain in water column or accumulate in sediments. Can contribute to reduction in light penetration;

Can reduce primary productivity;

Can adversely affect filter feeding organisms.

References